The engine does not know which solvent is in the loop. It compares what the plant is doing against what physics says a healthy unit should be doing, ranks the gaps, names the cause behind each one and prices the consequence. That works on a removal loop, and it works on the fired equipment where the site’s energy actually goes.
Same loop — one calibration passAcid gas and CO₂ removal loops
What goes wrongFoaming, absorber flooding, lean/rich exchanger fouling, reboiler scaling and corrosion, filter plugging, solvent degradation.
What comes backThe closest unit on this page to the one we have already calibrated: absorber, flash, lean/rich exchange, regenerator and reboiler. The solvent changes — aMDEA, hot potassium carbonate, a physical solvent — the structure and the failure modes do not.
Next — calibration workSteam reforming and hydrogen production
What goes wrongCatalyst deactivation and carbon lay-down, tube skin temperature drift, approach to equilibrium falling away, shift conversion loss, PSA recovery decay.
What comes backMeasured conversion against modelled conversion, with the shortfall attributed to catalyst, to firing or to feed — and the fuel each of those is costing per hour.
Wider siteSteam crackers and fired heaters
What goes wrongCoil fouling and coking, run length shortening, excess air and burner imbalance, selectivity drifting away from the target cut.
What comes backDecoking decided on a modelled cost curve rather than a calendar, and firing efficiency reported in fuel, money and CO₂ rather than as a percentage nobody can act on.
Wider siteDistillation trains and separation
What goes wrongFlooding and weeping, tray or packing damage, reflux and reboiler imbalance, product specification giveaway that nobody prices.
What comes backSeparation efficiency against design, and the reboiler duty being spent to make a product purer than the specification requires — usually the quietest large loss on a chemical site.
Wider siteCompressors, refrigeration and rotating equipment
What goes wrongPolytropic efficiency decay, fouled intercoolers, surge margin, seal and lube systems, refrigeration approach loss.
What comes backWhich constraint is actually binding right now, how far the unit is from it, and what that distance is worth per hour of run time.
Wider siteSteam, power and site heat integration
What goes wrongLetdown that should have been a turbine, failed traps, imported power bought while steam is vented, and a site balance nobody has closed since commissioning.
What comes backA closed site energy balance, modelled against measured, so every unit’s share of the energy bill is a number rather than an allocation.